In this study, we implement a phase-field model to investigate two electrochemical reaction models: the Butler–Volmer and the Marcus–Hush–Chidsey formulation. We assess their effect on the spatial and temporal evolution of the FePO 4 and LiFePO 4 phases. . Optimizing the charging rate is crucial for enhancing lithium iron phosphate (LFP) battery performance. The substantial heat generation during high C-rate charging poses a significant risk of thermal runaway, necessitating advanced thermal management strategies. The low solubility of lithium (Li) in some of these host lattices cause phase changes, which for example happens in FePO. .
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